Enhancement of Adsorption of Paracetamol Drug on Carbon Nanotubes concerning Wastewater Treatment

Aseel M. Aljeboree1

Ahmed B. Mahdi2

Waleed Khaled Younis Albahadly3

Samar Emad Izzat4

Munthir Mohammed Radhy AL Kubaisy5

Fadhil Muhsin Abid6

Ahmed Kareem Obaid Aldulaimi7

Ayad F. Alkaim1,Email

1Department of Chemistry, College of Science for Women, University of Babylon, Hillah, Babylon, 51002, Iraq
2Department of Anesthesia Techniques, Al-Mustaqbal University College, Hillah, Babylon, 51002, Iraq
3College of Pharmacy, Iraq College of Pharmacy, University of Al-Ameed, Karbala, 56001, Iraq
4Al-Nisour University College, Baghdad, 10081, Iraq
5College of Pharmacy, The University of Mashreq, Baghdad, 11001, Iraq
6Al-Hadi University College, Department of Medical Laboratory Techniques, Baghdad, 10011, Iraq
7Department of Pharmacy, Al-Zahrawi University College, Karbala, 56001, Iraq

Abstract

It is essential to eliminate antibiotics from water due to their possible harm to living creatures and the growth of resistant microorganisms. The present study focuses on paracetamol inhibition utilizing carbon nanotubes (CNTs). Fourier transform infrared, field emission-scanning electron microscopy, and transmission electron microscopy techniques were used to study the fabricated CNTs’ physical and chemical properties. Several concentrations of medication (10-100 mg L-1), pH solution (2.2–10.2), the weight of CNTs (0.002-0.08 g), and temperature solution (10-30 oC) were used to estimate the adsorption studies. The obtained results indicated that a concentration of 50 mg L-1, a pH of 6.6, an adsorbent amount of 0.02 g, and a contact time of 2 h  are optimal conditions for removing 95.40% of the drug from water. The results of the adsorption study indicate that the percentage of removal increases as the weight of the surfaces increases. The thermodynamic factors (∆Go), (∆Ho), and (∆So) were estimated, and the negative values of ∆Go indicated that the removal method was spontaneous at various temperatures. The correlation coefficient value at R2 = 0.98881 indicates that the adsorption method has high applicability concerning the second-order model. In contrast, the applicability of the first-order model and Elkovich equation are moderate, as indicated by the correlation coefficient values of R2 = 0.70844 and R2 = 0.84540, respectively. Based on the findings, the prepared CNTs may serve as a promising, environmentally friendly, cost-effective, and effective material for paracetamol drugs.