Hybrid Solid State Supercapacitors (HSSC’s) for High Energy & Power Density: An Overview
Satyajeet S. Patil, Tejasvinee S. Bhat, Aviraj M. Teli, Sonali A. Beknalkar, Sarika B. Dhavale, Minaj M. Faras, Milind M. Karanjkar and Pramod S. Patil
Satyajeet S. Patil1
Tejasvinee S. Bhat1,2
Aviraj M. Teli1
Sonali A. Beknalkar1
Sarika B. Dhavale1
Minaj M. Faras1
Milind M. Karanjkar3
Pramod S. Patil1,2*,Email
1Thin Film Materials Laboratory, Department of Physics, Shivaji University, Kolhapur, M.S., 416004, India
2School of Nanoscience and Technology, Shivaji University, Kolhapur, M.S., 416004, India
3Department of Physics, Vivekanand College, Kolhapur, M.S., 416003, India
Abstract
A hybrid supercapacitor (HSC) is a supercapacitor (SC) based on two different electrode materials. One electrode is based on battery type faradic reactions (Also known as extrinsic pseudocapacitor), and the other one is based on the electric double-layer capacitor (non-faradic, known as intrinsic pseudocapacitor). In HSC, generally negative electrode material includes carbon-based materials (such as activated carbon, carbon nanotubes (CNT’s) and graphene), metal oxides (V2O5 and MoO3), and their composites, while positive electrode materials are Ni, Co-based, mixed metal oxide, binary metal-based, layered double hydroxide (LDH) based materials etc. The synergy between high conductivity, surface area of the negative electrode and architectures, heterostructures of positive electrodes used to improve the overall electrochemical performances of the HSC’s device. In this review, the basic charge storing mechanisms, a method for determination of capacitive and diffusion controlled contribution, is explained. This review highlights the importance of hybrid solid-state supercapacitors (HSSC’s) as energy storage devices. Finally, the recent advancement in the HSSC fields is discussed that will guide future work in the HSSC field.
Publication details
Received: 16 Aug 2020
Revised: 15 Sep 2020
Accepted: 15 Sep 2020
Published online: 26 Sep 2020
Article type:
Review Paper
DOI:
10.30919/es8d1140
Volume:
12
Page:
38-51
Citation:
Engineered Science, 2020, 12, 38-51
Permissions:
Copyright
Number of downloads:
5419
Citation Information:
34
Description:
This review article focused on fundamental information about supercapacitors, their types, and elect....
This review article focused on fundamental information about supercapacitors, their types, and electrode materials for hybrid solid state supercapacitors.
This article is cited by 34 publications.
- Chaitali Jagtap, Vishal Kadam, Bhagyashri Kamble, P.E. Lokhande, Amir Pakdel, Deepak Kumar, R. Udayabhaskar, Amol Vedpathak, N.B. Chaure, H.M. Pathan. Synergistic growth of cobalt hydroxide on reduced graphene oxide/nickel foam for supercapacitor application. Journal of Energy Storage 2024, 83, 110666, DOI: 10.1016/j.est.2024.110666
- Yize Gong, Song Xie, Xianke Ping, Guishu Li, Junxian He. The influence of overcharge and discharge rate on the thermal safety performance of lithium-ion battery under low air pressure. Ionics 2022, 28, 4653, DOI: 10.1007/s11581-022-04720-2
This article is cited by 34 publications.
- Chaitali Jagtap, Vishal Kadam, Bhagyashri Kamble, P.E. Lokhande, Amir Pakdel, Deepak Kumar, R. Udayabhaskar, Amol Vedpathak, N.B. Chaure, H.M. Pathan. Synergistic growth of cobalt hydroxide on reduced graphene oxide/nickel foam for supercapacitor application. Journal of Energy Storage 2024, 83, 110666, DOI: 10.1016/j.est.2024.110666
- Yize Gong, Song Xie, Xianke Ping, Guishu Li, Junxian He. The influence of overcharge and discharge rate on the thermal safety performance of lithium-ion battery under low air pressure. Ionics 2022, 28, 4653, DOI: 10.1007/s11581-022-04720-2
- Vaibhav R. Shrikhande, Santosh J. Uke, Satish P. Mardikar, Gajanan N. Chaudhari, Anjali B. Bodade. Facile hydrothermal growth of co-doped SrTiO₃ on 3D nickel foam for advanced binder-free supercapacitor electrodes. Ionics 2025, 31, 9727, DOI: 10.1007/s11581-025-06533-5
- Xiaoyu Zhao, Yingbing Zhang, Yongdan Hou, Zijian Zhao, Yaxin Gong, Yanfei Wang, Huige Wei, Vilas G. Pol. Synergistic effect of tailored 3D/2D Ti3C2Tx/CoS2/C nanostructured composite anode for significantly enhanced Li-ion storage. Advanced Composites and Hybrid Materials 2022, 5, 2988, DOI: 10.1007/s42114-022-00527-x
- Keqi Qu, Zhe Sun, Cai Shi, Weicong Wang, Lidong Xiao, Jiangyang Tian, Zhanhua Huang, Zhanhu Guo. Dual-acting cellulose nanocomposites filled with carbon nanotubes and zeolitic imidazolate framework-67 (ZIF-67)–derived polyhedral porous Co3O4 for symmetric supercapacitors. Advanced Composites and Hybrid Materials 2021, 4, 670, DOI: 10.1007/s42114-021-00293-2
- Kyle Jiang, Rosario A. Gerhardt. Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films. C 2021, 7, 70, DOI: 10.3390/c7040070
- R. Amirthavalli, A. Nishara Begum, M. Parthibavarman, M. Tamilchezhiyan. Enhancing the electrochemical properties of Sr-doped spinel copper cobaltite CuCo2O4 for supercapacitor application. Ionics 2025, 31, 5217, DOI: 10.1007/s11581-025-06241-0
- Noor Ul Haq Liyakath Ali, Sindhuja Manoharan, Parthiban Pazhamalai, Sang-Jae Kim. CuMoO4 nanostructures: A novel bifunctional material for supercapacitor and sensor applications. Journal of Energy Storage 2022, 52, 104784, DOI: 10.1016/j.est.2022.104784
- Abhishek A. Kulkarni, Satyajeet S. Patil, Neha K. Gaikwad, Rushikesh M. Dahotre, Ankita P. Salunkhe, Pramod S. Patil, Tejasvinee S. Bhat. Unveiling the impact of reaction temperature on hydrothermally synthesized nickel phosphate hydrate for supercapacitors. Inorganic Chemistry Communications 2023, 158, 111635, DOI: 10.1016/j.inoche.2023.111635
- Haeji Kim, Jun Young Cheong, Byungil Hwang. Mini Review of Technological Trends of Flexible Supercapacitors Using Carbon Nanotubes. Journal of Natural Fibers 2023, 20, , DOI: 10.1080/15440478.2023.2204455
- Yiting Wu, Hongqiang Huang, Weiming Zhou, Chuanting You, Huilan Ye, Jia Chen, Shuo Zang, Juhua Yun, Xinqi Chen, Liwei Wang, Zhanhui Yuan. High-Porosity Lamellar Films Prepared by a Multistage Assembly Strategy for Efficient Photothermal Water Evaporation and Power Generation. ACS Applied Materials & Interfaces 2022, 14, 29099, DOI: 10.1021/acsami.2c05125
- Satyajeet S. Patil, Pramod S. Patil. Status review of nickel phosphides for hybrid supercapacitors. Nanoscale 2022, 14, 16731, DOI: 10.1039/D2NR05139G
- De Wang, Yanjing Wang, Zhenyu Fu, Yanbin Xu, Li-Xia Yang, Feng Wang, Xiaoling Guo, Wenjuan Sun, Zheng-Long Yang. Cobalt–Nickel Phosphate Composites for the All-Phosphate Asymmetric Supercapacitor and Oxygen Evolution Reaction. ACS Applied Materials & Interfaces 2021, 13, 34507, DOI: 10.1021/acsami.1c04614
- A. Sayah, A. Bahloul, F. Habelhames, N. Boumaza, Y. Ghalmi, A. Tounsi, L. Lamiri, B. Nessark, L. Ghelani, A. Chala. Electrodeposition mode effects on the electrochemical performance of cobalt sulfide material for supercapacitors. Ionics 2025, 31, 851, DOI: 10.1007/s11581-024-05903-9
- Yongpeng Ma, Xiubo Xie, Wenyue Yang, Zhipeng Yu, Xueqin Sun, Yuping Zhang, Xiaoyang Yang, Hideo Kimura, Chuanxin Hou, Zhanhu Guo, Wei Du. Recent advances in transition metal oxides with different dimensions as electrodes for high-performance supercapacitors. Advanced Composites and Hybrid Materials 2021, 4, 906, DOI: 10.1007/s42114-021-00358-2
- Shuyue Xu, Yibo Zhao, Wenjing He, Lu Chang, Mingyan Wang, Cheng Wang, Kean Wang, Minjie Cui, Yuchen Zhang. High-Mass-Loading Electrodes Prepared by Carbonizing P-Phenylenediamine-Modified Polyaniline Nanofibers. Energy & Fuels 2022, 36, 1129, DOI: 10.1021/acs.energyfuels.1c04139
- Palanisamy Elayarani, Thiyagarajan Sumathi, Ganesan Sivakumar, Selvam Pragadeswaran, Selvakumar Suthakaran, Subbarayan Sathiyamurthy, Jayasree Seshadhri, Manikandan Ayyar, Markasagayam Visagamani Arularasu. Hydrothermal synthesis of zinc molybdates (α-ZnMoO4) nanoparticles and its applications of supercapacitor and photocatalytic performances. Zeitschrift für Physikalische Chemie 2024, 238, 1019, DOI: 10.1515/zpch-2023-0531
- Shan Liu, Haishun Du, Kun Liu, Ming-Guo Ma, Ye-Eun Kwon, Chuanling Si, Xing-Xiang Ji, Sun-Eun Choi, Xinyu Zhang. Flexible and porous Co3O4-carbon nanofibers as binder-free electrodes for supercapacitors. Advanced Composites and Hybrid Materials 2021, 4, 1367, DOI: 10.1007/s42114-021-00344-8
- Shikhamir Eminov, Dilgam Tagiyev, Akif Aliyev, Khuraman Jalilova, Jafar Guliyev, Alovsat Rajabli, Gultakin Mammadova, Aysel Karimova, Samira Abdullayeva, Vusala Majidzade. Integration of supercapacitor with solar cell based on NiO 2 and CdS nanopillars embedded in porous anodic alumina templates . International Journal of Energy Research 2022, 46, 22134, DOI: 10.1002/er.8741
- Mamta Bulla, Sarita Sindhu, Annu Sheokand, Raman Devi, Vinay Kumar. Frontiers in transition metal oxide-based composites for high-performance supercapacitors: A comprehensive review. Inorganic Chemistry Communications 2024, 170, 113429, DOI: 10.1016/j.inoche.2024.113429
- Xiangping Li, Zhenping Su, Peng Liang, Jianguang Zhang. Construction of fungus waste-derived porous carbon as electrode materials for electrochemical supercapacitor. Biomass Conversion and Biorefinery 2023, 13, 6237, DOI: 10.1007/s13399-021-01612-9
- Satyajeet S. Patil, Pramod S. Patil. Transition metal pyrophosphate (MxP2O7): A new arrival in hybrid supercapacitors. Chemical Engineering Journal 2023, 455, 140639, DOI: 10.1016/j.cej.2022.140639
- Huayu Liu, Ting Xu, Qidi Liang, Qingshuang Zhao, Dawei Zhao, Chuanling Si. Compressible cellulose nanofibrils/reduced graphene oxide composite carbon aerogel for solid-state supercapacitor. Advanced Composites and Hybrid Materials 2022, 5, 1168, DOI: 10.1007/s42114-022-00427-0
- Aleksandar Dekanski. Challenges and doubts of electrochemical energy conversion and storage. Hemijska industrija 2022, 76, 43, DOI: 10.2298/HEMIND220201002D
- Zili Tang, Junsong Xia, Hang Yin, Guanghui Fu, Xitong Ai, Hailong Tang, Chaolong Yang, Lunjun Qu, Youbing Li. High-temperature-resistant barium strontium titanate @Ag/poly(arylene ether nitrile) composites with enhanced dielectric performance and high mechanical strength. Advanced Composites and Hybrid Materials 2022, 5, 823, DOI: 10.1007/s42114-021-00366-2
- Guodong Zhang, Weiqiang Cao, Haixia Zhang, Ying Hou, Junjie Guo. Facial Synthesis of Fe3O4/PPy Core–Shell Composite Electrode Material for Boosted Supercapacity. Energy & Fuels 2022, 36, 5018, DOI: 10.1021/acs.energyfuels.2c00659
- Neha K. Gaikwad, Satyajeet S. Patil, Abhishek A. Kulkarni, Rushikesh M. Dahotre, Ankita P. Salunkhe, Pramod S. Patil, Tejasvinee S. Bhat. Understanding the role of precursor concentration in the hydrothermal synthesis of nickel phosphate hydrate for supercapacitors. Journal of Materials Science: Materials in Electronics 2024, 35, , DOI: 10.1007/s10854-023-11883-9
- Chandni A P, Suvarna K. Subrahmanian, Binitha N. Narayanan. High cycling stability polyaniline/carbon sphere/graphene ternary nanocomposite cathode material for asymmetric supercapacitors. Materials Today Communications 2024, 41, 110416, DOI: 10.1016/j.mtcomm.2024.110416
- Edwin T. Mombeshora, Edigar Muchuweni, Hamed Hashemi. Applications of Graphene Derivatives in All‐Solid‐State Supercapacitors. ChemistrySelect 2024, 9, , DOI: 10.1002/slct.202404345
- M. Deepikaa, S. Karthickprabhu, K. Karuppasamy, M. Mahendran. Design and electrochemical profiling of Zn-MOF for next-generation supercapacitors. Ionics 2025, 31, 12103, DOI: 10.1007/s11581-025-06692-5
- Xiufang Dong, Xiaolong Zhao, Yanjun Chen, Chao Wang. Investigations about the influence of different carbon matrixes on the electrochemical performance of Na3V2(PO4)3 cathode material for sodium ion batteries. Advanced Composites and Hybrid Materials 2021, 4, 1070, DOI: 10.1007/s42114-021-00319-9
- Nitika Arya, Yadu Chandran, Bhumit Luhar, Priyanka Kajal, Satvasheel Powar, Viswanath Balakrishnan. Porosity-Engineered CNT-MoS2 Hybrid Nanostructures for Bipolar Supercapacitor Applications. ACS Applied Materials & Interfaces 2023, 15, 34818, DOI: 10.1021/acsami.3c05098
- Khuram Shahzad Ahmad, Shaan Bibi Jaffri, Kemilaben Chaudhary, Ram K. Gupta, Ghulam Abbas Ashraf, Nouf H. Alotaibi. Harnessing energy sustainability: synthesis of BaS2:CoS:MnS semiconductor trichotomous chalcogenide for superior supercapacitor device operation. Ionics 2025, 31, 2109, DOI: 10.1007/s11581-025-06062-1
- Chao Ding, Nannan Zhu, Xuehui Wang, A. Alhadhrami, M. H. H. Mahmoud, Mohamed M. Ibrahim, Que Huang, Changcheng Liu, Mina Huang, Jian Wang. Experimental study on the burning behaviors of 21700 lithium-ion batteries with high specific energy after different immersion duration. Advanced Composites and Hybrid Materials 2022, 5, 2575, DOI: 10.1007/s42114-022-00536-w
General Links :
Copyright © 2025 Engineered Science Publisher, All Rights Reserved