Improvement of Bio-oil Quality through the use of Natural Zeolite Catalysts in the Fast Pyrolysis of Cassava Rhizomes using a Free-Fall Reactor

Koson Rueangsan1

Pakkip Kraisoda1

Homhuan Tasarod2,Email

Sayun Phansomboon3

Piyachat Wiriyaampaiwong4

Nuttapan Promsampao5 

Somsuk Trisupakitti6

1Department of Agricultural Machinery Engineering, Faculty of Engineering and Industrial, Kalasin University, Mueang District, Kalasin,46000, Thailand
2Department of Electrical Engineering, Faculty of Engineering and Industrial, Kalasin University, Mueang District, Kalasin ,46000, Thailand
3Department of Plant Production Technology, Faculty of Agricultural Technology, Kalasin University, Mueang District, Kalasin, 46000,Thailand
4Department of Biotechnology. Faculty of Agricultural Technology, Kalasin University, Mueang District, Kalasin 46000, Thailand
5Department of Mechanical and Manufacturing Engineering, Faculty of Science and Engineering, Kasetsart University, Chalermphrakiat Sakon Nakhon Province Campus, Sakon Nakhon 47000, Thailand
6Department of Chemistry, Faculty of Science and Technology, Rajabhat Maha Sarakham University, Mueang District, Maha Sarakham 44000, Thailand

Abstract

This research investigated the properties of bio-oil derived from cassava rhizomes using natural zeolite catalyst within the hot gas filtration unit of a free-fall reactor. The reactor was controlled at 450, 500, and 550°C, while the condenser unit was maintained at a constant temperature. Cassava rhizome particle, 0.2 to 0.5 mm in size, were input at 200 g/hr. Results indicated a maximum bio-oil yield of approximately 60 wt% at 500°C without catalysis. Bio-oil collected from the electrostatic precipitator exhibited higher density and viscosity compared to that from the water-cooled condenser, and these properties were not significantly affected by the catalyst. However, the catalyst enhanced the bio-oil’s higher heating value (HHV) by approximately 17%, potentially due to increased hydrocarbon content and decreased oxygen levels, particularly in the electrostatic precipitator-derived bio-oil. These findings suggest the potential of natural zeolite catalysts to improve bio-oil quality.