Jamun Seed (Syzygium Cumini) Biochar as a Potential Adsorbent for Environmental Applications

Asha Ripanda1,Email

Mwemezi J. Rwiza2

S. Giridhar Reddy3,Email

Elias Charles Nyanza4

Ramadhani Bakari5

Hossein Miraji1

C. R. Ravikumar6

H. C. Ananda Murthy7,8

Saidi Ali Hamad Vuai9

Revocatus L. Machunda2

Sri Hari Kumar Annamareddy10

1Department of Chemistry, College of Natural and Mathematical Sciences, University of Dodoma, P.O. Box 338, Dodoma, 11090, Tanzania
2School of Materials, Energy, Water and Environmental Sciences (MEWES), P.O. Box 447, The Nelson Mandela African Institution of Science and Technology (NM-AIST), Tengeru Campus, Arusha, 23100, Tanzania 
3Department of Physical Sciences, Amrita School of Engineering, Bengaluru Campus, Amrita Vishwa Vidyapeetham, Bengaluru, 560035, India
4Department of Environmental and Occupational Health, School of Public Health, Catholic University of Health and Allied Sciences (CUHAS),  Mwanza, 1464, Tanzania
5Department of Petroleum and Energy Engineering, The University of Dodoma, P.O. Box, Dodoma, 11090, Tanzania
6Research Centre, Department of chemistry, East West Institute of Technology, Bangalore, 560091, India
7Department of Applied Sciences, Papua New Guinea University of Technology, Lae, Morobe, Province, 411, Papua New Guinea
8Department of Prosthodontics, Saveetha Dental College and Hospital, Saveetha Institute of Medical and Technical Science (SIMAT), Saveetha University, Chennai, Tamil Nadu, 600077, India
9Mbeya University of Science and Technology, Mbeya, 5311, Tanzania
10Department of Chemical and Petrochemical Engineering, University of Nizwa, Birkat Al-Mouz, 616, Sultanate of Oman

Abstract

This study investigates the properties and adsorption performance of jamun seed biochar (JS biochar) produced through calcination at varying temperatures. Elemental analysis reveals that the carbon content significantly increases from 64.25 to 87.93 wt.% as calcination temperature rises from 400 to 600 °C, while nitrogen content remains within the range of 2 to 2.29 wt.%. The biochar's surface characteristics, with a maximum specific surface area of 261.2 m²/g, demonstrate strong adsorption capacity for small organic molecules, including ciprofloxacin (555.55 mg/g) and lamivudine (400 mg/g). The identified functional groups, including hydroxyl and carbonyl groups, enhance adsorption through mechanisms such as hydrogen bonding and electrostatic interactions. The observed porous, rough surface morphology supports the material's effectiveness as an adsorbent. The results demonstrate JS biochar’s high adsorption capacity, governed by a synergistic interplay of physisorption and chemisorption. This research underscores the potential of JS biochar as a sustainable and effective solution for environmental remediation, particularly in mitigating aqueous pollutants. The findings offer valuable insights for optimizing biochar properties to improve adsorption efficiency, thereby promoting sustainable waste management and environmental remediation.