Bismuth Sulfide and Antimony Sulfide-Based Solar Cells: A Review
Abhijit T. Supekar, Pankaj K. Bhujbal, Supriya A. Salunke, Sopan M. Rathod, Shashikant P. Patole and Habib M. Pathan
Abhijit T. Supekar1,2
Pankaj K. Bhujbal2,3
Supriya A. Salunke2
Sopan M. Rathod1
Shashikant P. Patole4
Habib M. Pathan2,4,*,Email
1 Abasaheb Garware Arts and Science College, Pune, 411004, India
2 Advanced Physics Laboratory, Department of Physics, Savitribai Phule Pune University, Pune, 411007, India
3 Department of Applied Physics, Defence Institute of Advanced Technology, Pune, 411025, India
4 Department of Physics, Khalifa University of Science and Technology, Abu Dhabi, 127788, United Arab Emirates
Abstract
Quantum dot-sensitized solar cells are the most promising alternative to third-generation solar cells due to their versatile properties, such as maximum light-harvesting ability, tunable absorption range, solution processability, and good stability, compared to organic dyes. Various narrow band gap semiconducting materials are available to sensitize wide band gap semiconducting materials. CdS, PbS, CdSe, CdTe, Bi2S3, Sb2S3, etc., are used as sensitizers among all of these sensitizers. Bismuth Sulfide (Bi2S3) and antimony sulfide (Sb2S3) are the most promising but less studied compounds due to their lower stability with liquid electrolytes. As compared to other metal chalcogenides Bi2S3 and Sb2S3 are less toxic. Both are the most abundant elements, band gap of Bi2S3 and Sb2S3 is suitable for optoelectronic devices. In the present review, we discuss various optoelectronic properties of Bi2S3 and Sb2S3, synthesis techniques, properties of the material, cell fabrication, and stability issues of Bi2S3, Sb2S3 based solar cells, and some strategies that improve the performance of Bi2S3- and Sb2S3 based solar cells.
Publication details
Received: 14 Aug 2022
Revised: 19 Mar 2023
Accepted: 19 Mar 2023
Published online: 20 Mar 2023
Article type:
Review Paper
DOI:
10.30919/esee8c848
Volume:
19
Article :
848
Citation:
ES Energy & Environment, 2023, 19, 848
Permissions:
Copyright
Number of downloads:
403
Citation Information:
12
Description:
The present review article mentioned the importance of nontoxic Bismuth Sulfide and Antimony Sulfide....
The present review article mentioned the importance of nontoxic Bismuth Sulfide and Antimony Sulfide as a sensitizer and their synthesis methods it also includes various techniques that improve the performance of bismuth sulfide and antimony sulfide-based solar cells.
This article is cited by 12 publications.
- Abhijit T. Supekar, Maruti V. Salve, Shivkumar S. Patil, Pankaj K. Bhujbal, Almas M. Mujawar, Nandu B. Chaure, Shoyebmohamad F. Shaikh, Sopan M. Rathod, Habib M. Pathan. Sb2S3 coated titania photoelectrode: fabrication and its properties. Journal of Materials Science: Materials in Electronics 2025, 36, , DOI: 10.1007/s10854-025-15392-9
- Shital M. Sonar, Zhanhu Guo, Mohamed M. Ibrahim, Gaber A. M. Mersal, Hemant S. Tarkas, Prakash B. Ahirrao. Study of photoelectrochemical (PEC) solar cell properties of n-type bismuth sulfide (n-Bi2S3)/p-type copper (I) iodide (p-CuI) heterojunction synthesized by SILAR. Journal of Materials Science: Materials in Electronics 2024, 35, , DOI: 10.1007/s10854-024-13310-z
This article is cited by 12 publications.
- Abhijit T. Supekar, Maruti V. Salve, Shivkumar S. Patil, Pankaj K. Bhujbal, Almas M. Mujawar, Nandu B. Chaure, Shoyebmohamad F. Shaikh, Sopan M. Rathod, Habib M. Pathan. Sb2S3 coated titania photoelectrode: fabrication and its properties. Journal of Materials Science: Materials in Electronics 2025, 36, , DOI: 10.1007/s10854-025-15392-9
- Shital M. Sonar, Zhanhu Guo, Mohamed M. Ibrahim, Gaber A. M. Mersal, Hemant S. Tarkas, Prakash B. Ahirrao. Study of photoelectrochemical (PEC) solar cell properties of n-type bismuth sulfide (n-Bi2S3)/p-type copper (I) iodide (p-CuI) heterojunction synthesized by SILAR. Journal of Materials Science: Materials in Electronics 2024, 35, , DOI: 10.1007/s10854-024-13310-z
- Seung Geun Jo, Gil‐Ryeong Park, Jemin Kim, Do Hyun Ahn, Rahul Ramkumar, Sun‐I Kim, Duck Hyun Lee, Jung Woo Lee. Microwave‐assisted control of PtNi nanoalloy clusters on the nitrogen‐doped graphene oxide for energy conversion with oxygen reduction reaction and hydrogen evolution reaction. EcoMat 2024, 6, , DOI: 10.1002/eom2.12499
- Abhijit T. Supekar, Pankaj K. Bhujbal, Almas M. Mujawar, Sandesh R. Jadkar, Shoyebmohamad F. Shaikh, Sopan M. Rathod, Suhas Kowshik, Nithesh Naik. Synthesis of Bi2S3-sensitized TiO2 photoanodes for enhanced photovoltaic performance in solar cell application. Journal of Materials Science: Materials in Electronics 2024, 35, , DOI: 10.1007/s10854-024-13181-4
- V. Gopala Krishna, G. Phaneendra Reddy, N. Revathi, K. T. Ramakrishna Reddy. Influence of sulfurization time on the properties of Bi2S3 films synthesized via chemical bath deposition. Journal of Materials Science: Materials in Electronics 2025, 36, , DOI: 10.1007/s10854-025-15528-x
- Stefania Wolff, Wiktoria Lipińska, Justyna Gumieniak, Agnieszka Kramek, Karol Załęski, Emerson Coy, Natalia A. Wójcik, Katarzyna Siuzdak. Solvent Selection as a Key Factor in the Performance of Semitransparent Heterojunctions Composed of Hydrogenated Nanotubes and Bismuth Sulfides. ACS Applied Materials & Interfaces 2025, 17, 6728, DOI: 10.1021/acsami.4c18233
- Dekai Meng, Yunjie Ju, Ailing Xu, Yonggui Wang, Dong Wang, Yanjun Xie, Zefang Xiao, Haigang Wang. Carboxymethyl Cellulose Enhanced Polymeric Form Stable Phase Change Materials with Reversible Transparency for Energy Storage. ACS Sustainable Chemistry & Engineering 2024, 12, 15623, DOI: 10.1021/acssuschemeng.4c05951
- V. Gopala Krishna, G. Phaneendra Reddy, N. Revathi, K.T. Ramakrishna Reddy. Comprehensive physical and chemical properties of sulfurized Bi2S3 films prepared by CBD process. Next Materials 2025, 8, 100566, DOI: 10.1016/j.nxmate.2025.100566
- Pratik Zala, Kishan Panchal, Vardhan Shah, Devanshi Zala, Abhijit Ray. Pyrolysis temperature-controlled structure and properties of spray deposited n-type Sb2S3 thin films for photoelectrochemical applications. Physica B: Condensed Matter 2025, 716, 417710, DOI: 10.1016/j.physb.2025.417710
- Sangsu Kim, Chang Min Lee, Syed Hamad Ullah Shah, Myung-Chul Jung, Sang Geul Lee, Chul Hoon Kim, Hyun Jae Lee, Chansun Park, Jung-Yeol Yeom, Seung Yoon Ryu, Hyojung Kim, Hochun Park, Won-Young Jeong, Shinhaeng Cho. Radiation Tolerance of Organohalide-Based Perovskite Solar Cells under 6 MeV Electron Beam Irradiation. The Journal of Physical Chemistry C 2024, 128, 885, DOI: 10.1021/acs.jpcc.3c06128
- Xin Pan, Li Zhou, Gang Wang, Ahmed M. Fallatah, Miaoda Yuan, Xiangning Zhang, Daqing Tan, Juanna Ren, Abdulraheem S. A. Almalki, Mohamed M. Ibrahim, Mengyao Dong, Zhanhu Guo. Study on the damage characteristics of high-temperature superconducting cable insulation under air gap discharge. Journal of Materials Science: Materials in Electronics 2024, 35, , DOI: 10.1007/s10854-024-13642-w
- Jesús Alba-Cabañas, Roberto Speranza, Alessandro Pedico, Andrea Lamberti, Lídice Vaillant-Roca. Enhancing coating uniformity and performance with zinc oxide nanoparticles interface layer in dye-sensitized cells. Materials Science and Engineering: B 2024, 310, 117748, DOI: 10.1016/j.mseb.2024.117748
General Links :
Copyright © 2025 Engineered Science Publisher, All Rights Reserved