Dielectric Properties and Thermal Conductivity of Polyvinylidene Fluoride Synergistically Enhanced with Silica@Multi-walled Carbon Nanotubes and Boron Nitride
Zijian Wu, Xuefei Wang, Sri Hari Kumar Annamareddy, Shunying Gao, Qi Xu, Hassan Algadi, Deepak Sridhar, Priyanka Wasnik, Ben Bin Xu, Ling Weng, and Zhanhu Guo
1Department of Material Science and Technology, Harbin University of Science and Technology, Harbin 150040，China.
2Key Laboratory of Engineering Dielectric and Its Application Technology of Ministry of Education, Harbin University of Science and Technology, Harbin 150040，China.
3Chemical and Petrochemical Engineering Department, College of Engineering and Architecture, University of Nizwa, Birkat Al Mouz, Nizwa, Sultanate of Oman.
4Department of Electrical Engineering, Faculty of Engineering, Najran University, P. O. Box 1988, Najran, 11001, Saudi Arabia
5Zentek Ltd. 24 Corporate Crt, Guelph, Ontario, N1G 5G5 Canada.
6Mechanical and Construction Engineering, Faculty of Engineering and Environment, Northumbria University, Newcastle Upon Tyne, NE1 8ST, UK.
Abstract
There is an urgent need for polymer composites with high thermal conductivity and electrical insulation in microelectronic packaging. Due to their fascinating chemical and physical properties, multi-walled carbon nanotubes (MWCNTs) have enabled major achievements in polymer composites fields as a reinforcement filler. Nevertheless, high conductivity of raw MWCNTs (R-MWCNTs) was an obstacle to wider application of the CNTs in some special fields, which require outstanding thermal conductivity and insulation properties simultaneously. In this work, silica@MWCNTs were prepared to reduce the electrical conductivity. The composites were prepared by doping BN and silica@MWCNTs through hot press method. The results showed that the thermal conductivity of BN-SiO2@MWCNT/PVDF was higher than that of BN/PVDF and pure PVDF. When the content of BN was 30wt%, the thermal conductivity of BN-SiO2@MWCNT/PVDF increased to 0.4084W/(m•K), which was 170% higher than that of pure PVDF. The dielectric constant, dielectric loss and conductivity of PVDF increased when only MWCNT was added, while the dielectric constant, dielectric loss and conductivity of the composite decreased with the increase of BN content after adding BN.
Publication details
Received: 03 Nov 2022
Revised: 16 Mar 2023
Accepted: 19 Mar 2023
Published online: 19 Mar 2023
Article type:
Research Paper
DOI:
10.30919/esmm5f847
Volume:
22
Article :
847
Citation:
ES Materials & Manufacturing, 2023, 22, 847
Permissions:
Copyright
Number of downloads:
4159
Citation Information:
41
Description:
The good synergy between surface-insulated carbon nanotubes and boron nitride facilitates the increa....
The good synergy between surface-insulated carbon nanotubes and boron nitride facilitates the increase in thermal conductivity of PVDF composites.
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