Hydrogen Storage on Lithium Chloride/Lithium Bromide Surface at Cryogenic Temperature
Gourisankar Roymahapatra, Mrinal Kanti Dash, Anjana Ghosh, Abhishek Bag, Santanu Mishra and Sibaprasad Maity
Gourisankar Roymahapatra1,#,*,Email
Mrinal Kanti Dash1,2,#
Anjana Ghosh1,3,4
Abhishek Bag1,2
Santanu Mishra1
Sibaprasad Maity1
1 School of Applied Science and Humanities, Haldia Institute of Technology, Haldia, 721657, India
2 Department of Chemistry, Cooch Behar Panchanan Barma University, Cooch Behar, 736101, India
3 Department of Chemical Engineering, Haldia Institute of Technology, Haldia, 721657, India
4 A.B. Polypacks Pvt. Ltd., Howrah, 711409, India
# Authors share the first authorship.
Abstract
This article has expressed that Lithium chloride (LiCl) and Lithium bromide (LiBr) are good templates for low-temperature hydrogen storage. The structure and chemical reactivity of the derived templates were studied based on density functional theory (DFT). The adsorption process can be found in nature as quasisorption. The molecular hydrogen interacts with building blocks (with the Li+ center) through electrovalent interaction, and a single LiCl/LiBr molecule can absorb 10 H2 molecules with a high gravimetric weight percentage (32.00 for LiCl and 18.71 for LiBr), which is turn out to be promising systems according to the standard. The Gibbs free energy changes suggest a spontaneous hydrogen adsorption process at cryogenic temperature.
Publication details
Received: 05 Apr 2022
Revised: 17 Jul 2022
Accepted: 17 Jul 2022
Published online: 18 Jul 2022
Article type:
Research Paper
DOI:
10.30919/esee8c756
Volume:
18
Page:
90-100
Citation:
ES Energy & Environment, 2022, 18, 90-100
Permissions:
Copyright
Number of downloads:
5356
Citation Information:
5
Description:
At cryogenic temperatures, a LiCl/LiBr can spontaneously adsorb 10H2 molecules and can act as promis....
At cryogenic temperatures, a LiCl/LiBr can spontaneously adsorb 10H2 molecules and can act as promising hydrogen storage material.
Supplementary Information:
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