Synthesis of Three Dimensional Mo-Doped Nickel Sulfide Mesoporous Nanostructures/Ni Foam Composite for Supercapacitor and Overall Water Splitting
Songyang Li, Jincheng Fan, Shidong Li, Hongguang Jin, Wenbin Luo, Yong Ma, Jianghong Wu, Zisheng Chao, Nithesh Naik, Duo Pan and Zhanhu Guo
1 College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, Hunan, 410114, China
2 School of Material Science and Engineering, Shandong University of Science and Technology, Qingdao, 266590, China
3 College of Health Science and Environmental Engineering, Shenzhen Technology University, Shenzhen, Guangdong, 518118, China
4 Department of Mechanical & Manufacturing Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka, 576104, India
5 Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN, 37996, USA
6 Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, 450001, China
Abstract
3D Mo-doped Ni3S2 mesoporous nanostructures on Ni foam were successfully synthesized via the solvothermal method, which showed the superior properties for energy storage and conversion. As an electrode for supercapacitor, 3D Mo-doped Ni3S2 mesoporous nanostructures demonstrated a 604.4 μAh cm-2 specific capacity and good cycling stability. Furthermore, Mo-doped Ni3S2 mesoporous nanostructures exhibited superior hydrogen evolution reaction and oxygen evolution reaction properties and good cycle stability for water splitting. At 1.41 V, the electrolyzer made up of Mo-doped Ni3S2 mesoporous nanostructures reached the 10 mA cm-2 catalytic current density, demonstrating outstanding long-term durability. Furthermore, the physical characterization results and mechanism of the 3D Mo-doped Ni3S2 were investigated. Therefore, the study presents the great promise of the 3D Mo-doped Ni3S2 mesoporous nanostructures in energy conversion and storage.
Publication details
Received: 14 Aug 2021
Revised: 25 Jan 2022
Accepted: 03 Feb 2022
Published online: 07 Feb 2022
Article type:
Research Paper
DOI:
10.30919/esee8c646
Volume:
16
Page:
15-25
Citation:
ES Energy & Environment, 2022, 16, 15-25
Permissions:
Copyright
Number of downloads:
3279
Citation Information:
13
Description:
Three dimensional Mo-doped Ni3S2 mesoporous nanostructures have been successfully fabricated on Ni f....
Three dimensional Mo-doped Ni3S2 mesoporous nanostructures have been successfully fabricated on Ni foam by a facile solvothermal route, which demonstrated the superior galvanization charging/discharging (GCD), hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) performances at various temperatures. The study opens new the opportunities to develop the self-supported noble-metal-free nanostructures for sustainable energy systems.
Supplementary Information:
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