One-step Coassembled Nanocoatings on Paper for Potential Packaging Applications

Sonia E. Chavez1,2

Hao Ding1,2

Brandon L. Williams1,2

Sunghyun Nam3

Zaili Hou1,2

Dongqiao Zhang1,2

Luyi Sun1,2,4,*

Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut, 06269, USA

Department of Chemical and Biomolecular Engineering, University of Connecticut, Storrs, Connecticut, 06269, USA

United States Department of Agriculture, Agricultural Research Service, Southern Regional Research Center, New Orleans, LA, 70124, USA

Department of Biomedical Engineering, University of Connecticut, Storrs, Connecticut, 06269, USA

Abstract

Plastics films have been widely used in food packaging. But due to the environmental concerns of plastics films, there is a trend of replacing plastics films with paper for food packaging. To meet the requirements of packaging, the paper must be modified to improve its barrier properties. In this report, a sonication and dip coating method was developed to deposit a PVA/MMT nanocoating on two representative paper substrates: regular paper and cotton paper. The coated paper substrates were characterized by X-ray diffraction, scanning electron microscopy (SEM), water vapor transmission rate (WVTR), and microscale combustion calorimetry (MCC). The XRD results support the formation of well-aligned MMT nanosheets on paper substrates and the SEM images show that most pores on the substrates were covered by the nanocoatings, which leads to a drastic decrease in WVTR of the coated substrates. The nanocoatings also led to a minor improvement in flame retardancy. The results suggest that applying nanocoating is a promising approach to improve the barrier properties of paper for potential packaging applications.