Electrodeposition of Polyaniline Nanoparticles as High-Performance Electrode for Supercapacitor Application

Radhika S. Desai1

Vinayak S. Jadhav1

Divya D Lad1

Pramod S. Patil2,3

Dhanaji S. Dalavi1,Email

Department of Physics, Krishna Mahavidyalaya, Rethare Bk, Post-Shivnagar, Tal- Karad, Dist. Satara, Maharashtra, 415108, India
Department of Physics, Shivaji University, Kolhapur, Maharashtra, 416004, India
Department of Physics, National Dong Hwa University, Hualien, 97401, Taiwan

Abstract

Conducting polymers are garnering significant attention as promising electrode materials for energy storage applications. In this study, we present a straightforward and binder-free method for the electrodeposition of polyaniline (PANI) films on steel substrates. By optimizing the deposition time, we successfully synthesized PANI nanoparticles, leading to distinct morphological and electrochemical properties. Comprehensive structural and physicochemical characterization revealed that the PANI15 thin films, prepared at an optimal deposition time, exhibited a remarkable specific capacitance of 632.56 F g-1 at a scan rate of 10 mV s-1 in a 1 M sulfuric acid (H2SO4) electrolyte. This study demonstrates a practical approach to the design and synthesis of advanced electrode materials, paving the way for enhanced performance in energy storage applications. Our findings underscore the potential of electrodeposited PANI films as efficient materials for supercapacitors and other energy-related technologies.